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Recent development in chemical analyses of organic remains in archaeological ceramics gives new possibilities to the study of pottery use. They could be of crucial importance in assessing vessel’s use, especially when combined with contextual, technomorphological and use-alteration analysis data. Using the example of the late Neolithic pottery from Makriyalos, Northern Greece, we discuss some of the problems in determining the use of the vessels from archaeological context, and show the benefits of integrating chemical analysis of organic remains in approaching this issue.