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The embedded water pipe system is often used as a standard cooling technique during the construction of large-scale mass concrete hydrostructures. The prediction of the temperature distribution considering the cooling effects of embedded pipes plays an essential role in the design of the structure and its cooling system. In this study, the singular boundary method, a semi-analytical meshless technique, was employed to analyze the temperature distribution. A numerical algorithm solved the transient temperature field with consideration of the effects of cooling pipe specification, isolation of heat of hydration, and ambient temperature. Numerical results are verified through comparison with those of the finite element method, demonstrating that the proposed approach is accurate in the simulation of the thermal field in concrete structures with a water cooling pipe.