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In the title compound, [Mg(H2O)6](C8H6N5O2)Cl·2H2O, the MgII ion is surrounded by six water molecules, exhibiting a slightly distorted octahedral coordination. The pyridine and tetrazole rings are nearly coplanar, forming a dihedral angle of 4.63 (3)°. The complex cations, zwitterionic organic anions, Cl− anions and uncoordinated water molecules are connected by O—H...O, O—H...N and O—H...Cl hydrogen bonds, leading to the formation of a three-dimensional network.