Preparation and Application of Bismuth/MXene Nano-Composite as Electrochemical Sensor for Heavy Metal Ions Detection

oleh: Ying He, Li Ma, Liya Zhou, Guanhua Liu, Yanjun Jiang, Jing Gao

Format: Article
Diterbitkan: MDPI AG 2020-04-01

Deskripsi

A nano-form composite of MXenes (Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i>, T<i><sub>x</sub></i> = -O, -OH, -F) was synthesized through depositing bismuth-nanoparticle (BiNPs) onto Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i> sheets. Because of the preventive effect of the two-dimensional layered structure of Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i>, the nanoparticles of Bi were uniform and well attached on the Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i>. The obtained BiNPs/Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i> nano-composite was applied for sensors construction of electrochemical detecting of Pb<sup>2+</sup> and Cd<sup>2+</sup> heavy metal ions. The produced BiNPs@Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i>-based sensor showed high effective surface area and excellent conductivity. Also, the BiNPs were efficient for anodic-stripping voltammetric to detect heavy metal ions. After conditions optimization, the BiNPs@Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i> nano-sensor could detect Pb<sup>2+</sup> and Cd<sup>2+</sup> simultaneously and the detection limits were 10.8 nM for Pb<sup>2+</sup> and 12.4 nM for Cd<sup>2+</sup>. The BiNPs@Ti<sub>3</sub>C<sub>2</sub>T<i><sub>x</sub></i> was promising for detecting heavy metal ions due to their high surface area, fast electron-transfer ability, environmental friendliness, and facial preparation.