Find in Library

As many countries have tried to construct a hydrogen (H₂) society to escape the conventional energy paradigm by using fossil fuels, methane pyrolysis (MP) has received a lot of attention owing to its ability to produce H₂ with no CO₂ emission. In this study, a techno-economic analysis including a process simulation, itemized cost estimation, and sensitivity and scenario analysis was conducted for the system of thermal-based and catalyst-based MP (TMP-S1 and CMP-S2), and the system with the additional H₂ production processes of carbon (C) gasification and water–gas shift (WGS) reaction (TMPG-S3 and CMPG-S4). Based on the technical performance expressed by H₂ and C production rate, the ratio of H₂ combusted to supply the heat required and the ratio of reactants for the gasifier (C, Air, and water (H₂O)), unit H₂ production costs of USD 2.14, 3.66, 3.53, and 3.82 kgH₂⁻¹ from TMP-S1, CMP-S2, TMPG-S3, and CMPG-S4, respectively, were obtained at 40% H₂ combusted and a reactants ratio for C-Air-H₂O of 1:1:2. Moreover, trends of unit H₂ production cost were obtained and key economic parameters of the MP reactor, reactant, and C selling price were represented by sensitivity analysis. In particular, economic competitiveness compared with commercialized H₂ production methods was reported in the scenario analysis for the H₂ production scale and C selling price.