Formation of the BeH+ and BeD+ Molecules in Be+ + H/D Collisions Through Radiative Association

oleh: Péter Szabó, Szabolcs Góger, Magnus Gustafsson

Format: Article
Diterbitkan: Frontiers Media S.A. 2021-07-01

Deskripsi

Cross sections and rate coefficients for the formation of BeH+ and BeD+ molecules in Be+ + H/D collisions through radiative association are calculated using quantum mechanical perturbation theory and Breit-Wigner theory. The local thermodynamic equilibrium limit of the molecule formation is also studied, since the process is also relevant in environments with high-density and/or strong radiation fields. The obtained rate coefficients may facilitate the kinetic modelling of BeH+/BeD+ production in astrochemical environments as well as the corrosion chemistry of thermonuclear fusion reactors.