3-Bromo-2-[4-(methylsulfanyl)phenyl]-5,6,7,8-tetrahydro-1,3-benzothiazolo[3,2-a]imidazole

oleh: Alexander S. Bunev, Elena V. Sukhonosova, Vladimir E. Statsyuk, Gennady I. Ostapenko, Victor N. Khrustalev

Format: Article
Diterbitkan: International Union of Crystallography 2014-05-01

Deskripsi

In the title molecule, C16H15BrN2S2, the central imidazo[2,1-b]thiazole fragment is almost planar (r.m.s. deviation = 0.012 Å), and the fused 5,6,7,8-tetrahydrobenzene ring adopts an unsymmetrical half-chair conformation. The dihedral angle between the imidazo[2,1-b]thiazole and benzene planes is 18.25 (4)°. The terminal methylsulfanyl substituent lies practically within the benzene plane [the dihedral angle between the corresponding planes is 7.20 (10)°] and is turned toward the C—Br bond. In the crystal, molecules form infinite chains along [100] via secondary Br...N interactions [3.1861 (16) Å]. The chains are arranged at van der Waals distances.