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Plasmonic CO₂ methanation using γ-Al₂O₃-supported Ru nanorods was carried out under continuous-flow conditions without conventional heating, using mildly concentrated sunlight as the sole and sustainable energy source (AM 1.5, irradiance 5.5–14.4 kW·m⁻² = 5.5–14.4 suns). Under 12.5 suns, a CO₂ conversion exceeding 97% was achieved with complete selectivity towards CH₄ and a stable production rate (261.9 <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>mmol</mi><mo>·</mo><msubsup><mi mathvariant="normal">g</mi><mrow><mi>Ru</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup><mo>·</mo><msup><mi mathvariant="normal">h</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></semantics></math></inline-formula>) for at least 12 h. The CH₄ production rate showed an exponential increase with increasing light intensity, suggesting that the process was mainly promoted by photothermal heating. This was confirmed by the apparent activation energy of 64.3 kJ·mol⁻¹, which is very similar to the activation energy obtained for reference experiments in dark (67.3 kJ·mol⁻¹). The flow rate influence was studied under 14.4 suns, achieving a CH₄ production plateau of 264 µmol min⁻¹ (792 <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>mmol</mi><mo>·</mo><msubsup><mi mathvariant="normal">g</mi><mrow><mi>Ru</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msubsup><mo>·</mo><msup><mi mathvariant="normal">h</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></semantics></math></inline-formula>) with a constant catalyst bed temperature of approximately 204 °C.