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A series of benzotriazole, cyclic amides and pyrimidine derivatives, containing 2,6-di-<i>tert</i>-butyl-phenol fragments, were synthesized. The redox properties of obtained compounds were studied using the cyclic voltammetry on a platinum electrode in acetonitrile. The oxidation potentials of all substances were comparable to those of BHT. The obtained compounds were tested for their antibacterial activity, and <i>N</i>-(2-(3,5-di-<i>tert</i>-butyl-4-hydroxyphenyl)-2-oxoethyl)isatin (32 μg/mL) exerted good activity against <i>Staphylococcus aureus.</i>