Self-assembly directed one-step synthesis of [4]radialene on Cu(100) surfaces

oleh: Qing Li, Jianzhi Gao, Youyong Li, Miguel Fuentes-Cabrera, Mengxi Liu, Xiaohui Qiu, Haiping Lin, Lifeng Chi, Minghu Pan

Format: Article
Diterbitkan: Nature Portfolio 2018-08-01

Deskripsi

Radialenes have distinct structural, electronic and chemical properties from other hydrocarbons, but their synthesis remains a challenge. Here, the authors report a copper catalyzed one-step synthetic protocol of [4]radialene via the cyclotetramerization of phenylacetylene molecules upon thermal activation.