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Due to the low efficiency of thermoelectric generators (TEGs), many scholars have focused on the structural optimization of TEGs rather than on the optimization of the layout of thermoelectric modules. We aimed to investigate the effect of module layout on the output power of an automotive exhaust thermoelectric power generation system. The module spacing and module coverage ratio were compared under different working conditions based on a numerical simulation. The results show that, under high-temperature conditions, when the module spacing expands from 5 mm to 35 mm, the output power growth rate of modules of different sizes ranges between 8% and 9%. Moreover, under low-temperature conditions, a high coverage ratio of modules will not increase the total output power but, instead, make it decline. In fact, choosing a larger-size module can improve the temperature uniformity, thereby increasing the output power of the automotive thermoelectric power generation system. Hence, the present study has verified that, under different working conditions, different module layouts and module coverage ratios have an impact on the output power of the thermoelectric power generation system, which sheds new light on the improvement of automotive thermoelectric power generation systems.