trans-Bis(benzyldiphenylphosphane-κP)dichloridoplatinum(II)
oleh: Alfred Muller
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-12-01 |
Deskripsi
In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the PtII atom is occupied by two benzyldiphenylphosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C—H...Cl interactions generate infinite long chains along [01-1]. Additional C—H...π and π–π stacking interactions [centroid–centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] are observed.