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In search a hydrogen source, we synthesized TiO₂-Cu-graphene composite photocatalyst for hydrogen evolution. The catalyst is a new and unique material as it consists of copper-decorated TiO₂ particles covered tightly in graphene and obtained in a fluidized bed reactor. Both, reduction of copper from Cu(CH₃COO) at the surface of TiO₂ particles and covering of TiO₂-Cu in graphene thin layer by Chemical Vapour Deposition (CVD) were performed subsequently in the flow reactor by manipulating the gas composition. Obtained photocatalysts were tested in regard to hydrogen generation from photo-induced water conversion with methanol as sacrificial agent. The hydrogen generation rate for the most active sample reached 2296.27 µmol H₂ h⁻¹ g_cat⁻¹. Combining experimental and computational approaches enabled to define the optimum combination of the synthesis parameters resulting in the highest photocatalytic activity for water splitting for green hydrogen production. The results indicate that the major factor affecting hydrogen production is temperature of the TiO₂-Cu-graphene composite synthesis which in turn is inversely correlated to photoactivity.