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In Situ ZrB<sub>2</sub> Formation in B<sub>4</sub>C Ceramics and Its Strengthening Mechanism on Mechanical Properties
oleh: Wankai Yao, Junbing Yan, Xiangcheng Li, Pingan Chen, Yingli Zhu, Boquan Zhu
Format: | Article |
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Diterbitkan: | MDPI AG 2022-11-01 |
Deskripsi
In order to reduce the sintering temperature and improve the mechanical properties of B<sub>4</sub>C ceramics, ZrB<sub>2</sub> was formed in situ using the SPS sintering method with ZrO<sub>2</sub> and B<sub>4</sub>C as raw materials. Thermodynamic calculations revealed that CO pressure affected the formation of ZrB<sub>2</sub> at temperatures from 814 °C to 1100 °C. The experimental results showed that the ZrB<sub>2</sub> grain size was <5 µm and that the grains were uniformly distributed within the B<sub>4</sub>C ceramics. With an increase in ZrO<sub>2</sub> content, the Vickers hardness and flexural strength of the B<sub>4</sub>C ceramics first increased and then decreased, while the fracture toughness continuously increased. When the content of ZrO<sub>2</sub> was 15 wt%, the Vickers hardness, fracture toughness and flexural strength of B<sub>4</sub>C ceramics were 35.5 ± 0.63 GPa, 3.6 ± 0.24 MPa·m<sup>1/2</sup> and 403 ± 10 MPa, respectively. These results suggest that ZrB<sub>2</sub> inhibits B<sub>4</sub>C grain growth, eliminates crack tip stress, and provides fine grain to strengthen and toughen B<sub>4</sub>C ceramics.