catena-Poly[[[N,N′-bis(3-methoxybenzylidene)ethylenediamine]copper(I)]-μ-thiocyanato-κ2N:S]
oleh: Aliakbar Dehno Khalaji, Hassan Hadadzadeh, Kazuma Gotoh, Hiroyuki Ishida
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-01-01 |
Deskripsi
In the cyrstal structure of the title compound, [Cu(NCS)(C18H20N2O2)]n, the CuI atom is coordinated in a distorted tetrahedral geometry by two imino N atoms from a bidentate chelating Schiff base ligand, and one N and one S atoms from two thiocyanate anions. The thiocyanate anion bridges the CuI atoms, forming a zigzag chain along [101]. The Schiff base ligand adopts an E,E configuration and the dihedral angle between the terminal benzene rings is 53.68 (8)°.