Dichlorido{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethylformamide solvate
oleh: Hailong Wang, Daopeng Zhang, Laijin Tian, Li-Fang Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-11-01 |
Deskripsi
In the heterodinuclear complex of the title compound, [PbZn(C22H18N2O4)Cl2(C2H6OS)]·C3H7NO, the ZnII atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The PbII atom is coordinated in a distorted octahedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide molecule and one Cl atom. The dimethyl sulfoxide molecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2).