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In the molecule of the title compound, C14H14N2O5S2, the dihedral angle between the aromatic rings is 77.75 (9)°. The acetamide group is planar [maximum deviation = 0.002 (3) Å] and oriented at dihedral angles of 13.49 (21) and 73.94 (10)° with respect to the aromatic rings. An intramolecular C—H...O interaction results in the formation of a six-membered ring. In the crystal structure, intermolecular N—H...O and C—H...O interactions link the molecules into a three-dimensional network, forming R22(20) ring motifs.