Poly[1,4-bis(ammoniomethyl)cyclohexane [di-μ-chlorido-dichloridoplumbate(II)]]
oleh: Matthew Kyle Rayner, David Gordon Billing
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-06-01 |
Deskripsi
The title compound, {(C8H20N2)[PbCl4]}n, crystallizes as an layered inorganic–organic hybrid perovskite-type structure. Corner-sharing PbCl6 octahedra extend parallel to the ac plane. Adjacent layers are staggered relative to one another, with diammonium cations separating these layers. The cations exhibit overline{1} symmetry and interact with the inorganic sheets via N—H...Cl hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.