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Non-universal scaling behavior of polymer-metal composites across the percolation threshold
oleh: Maheswar Panda, V. Srinivas, A.K. Thakur
| Format: | Article |
|---|---|
| Diterbitkan: | Elsevier 2015-01-01 |
Deskripsi
The universal percolation behavior i.e. σeff(ω,fcon≈fc)∝ωx and εeff(ω,fcon≈fc)∝ω-y is satisfied; with x + y = 1, where σeff is the effective ac conductivity of the composite, ω is the frequency of applied ac signal and fc is percolation threshold. The exponents (x = 0.72 and y = 0.28) obtained under the inter-cluster polarization model for the case of 3D systems are consistent with the experimental values. The critical exponents s, s′ and t which characterize the divergence of εeff and σeff in the vicinity of fc show non-universal values. The non-universality of s, s′ and t is correlated with the extent of spatial connectivity of filler particles, which is reflected from the experimental values of loss tangent.