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Rapid Monitoring of Scale Precipitation and Inhibition in Geothermal Fluid Using Optical Fiber Sensor Based on Surface Plasmon Resonance
oleh: Ai Hosoki, Kifuyu Sugiura, Takuya Okazaki, Heejun Yang, Hideki Kuramitz, Akira Ueda, Amane Terai
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2024-09-01 |
Deskripsi
An optical fiber scale sensor based on the detection principle of surface plasmon resonance (SPR) was developed for the rapid, high-sensitivity, real-time evaluation of scale precipitation in geothermal fluids. The optical fiber SPR scale sensor was fabricated by depositing a gold thin film onto the surface of an optical fiber with an exposed core. The optimal gold film thickness of the sensor was determined to be 30 nm, which achieved a refractive index sensitivity of 2140 nm per refractive index unit. A field test was conducted using geothermal brine from the Obama Binary Geothermal Power Plant in Unzen, Nagasaki Prefecture. A conventional optical fiber scale sensor and the SPR sensor were simultaneously assessed using raw and pH-adjusted brines. For the SPR sensor, a peak shift of 0.27 nm/min was observed at a response time of 1 min, whereas no change in transmittance was observed for the conventional sensor until 180 min. After the experiments, a scanning electron microscopy-energy-dispersive spectroscopy analysis was conducted on the sensors, and the findings showed that the deposition of Mg-SiO<sub>2</sub> scale did not significantly differ between the two sensors. The developed SPR sensor achieved faster scale precipitation detection (tens of minutes to hours) than the conventional sensor.