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The daylighting environment in university gymnasiums affects daily teaching and sports training. However, direct sunlight, glare, and indoor overheating in summer are common problems. Semi-transparent photovoltaic glass can solve these issues by replacing shading facilities, blocking solar radiation, and generating electricity. This study examines the influence of different types of CdTe semi-transparent film photovoltaic glass on the daylighting environment of six typical university gymnasium skylights. The optimal types of CdTe semi-transparent film photovoltaic glass are determined by dynamic daylighting performance metrics DA, DAcon, DAmax, and UDI. The results show that, for instance, centralized rectangular skylights benefit from the 50–60% transmittance type, while centralized X-shaped skylights require the 70–80% transmittance type to enhance indoor daylighting. The research results offer specific recommendations based on skylight shapes and photovoltaic glass types and can provide a reference for the daylighting design of university gymnasium buildings with different forms of photovoltaic skylights in the future.