Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Relation between photoionisation cross sections and attosecond time delays
oleh: Jia-Bao Ji, Anatoli S Kheifets, Meng Han, Kiyoshi Ueda, Hans Jakob Wörner
Format: | Article |
---|---|
Diterbitkan: | IOP Publishing 2024-01-01 |
Deskripsi
Determination and interpretation of Wigner-like photoionisation delays is one of the most active fields of attosecond science. Previous results have suggested that large photoionisation delays are associated with structured continua, but a quantitative relation between photoionisation cross sections and time delays has been missing. Here, we derive a Kramers–Kronig-like relation between these quantities and demonstrate its validity for (anti)resonances. This new concept defines a topological analysis, which rationalises the sign of photoionisation delays and thereby sheds new light on a long-standing controversy regarding the sign of the photoionisation delay near the Ar 3 s Cooper minimum. Our work bridges traditional photoionisation spectroscopy with attosecond chronoscopy and offers new methods for analysing and interpreting photoionisation delays.