Bis(thiocyanato-κN)[tris(pyridin-2-ylmethyl)amine-κ4N]iron(II)
oleh: Jing-Wei Dai, Zhao-Yang Li, Osamu Sato
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2014-02-01 |
Deskripsi
In the title complex, [Fe(NCS)2(C18H18N4)], the FeII cation is chelated by a tris(2-pyridylmethyl)amine ligand and coordinated by two thiocyanate anions in a distorted N6 octahedral geometry. In the crystal, weak C—H...S hydrogen bonds and π–π stacking interactions between parallel pyridine rings of adjacent molecules [centroid–centroid distance = 3.653 (3) Å] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124 (9) Å3, which are free of solvent molecules.