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Spin-Orbital Excitations in Ca_{2}RuO_{4} Revealed by Resonant Inelastic X-Ray Scattering
oleh: L. Das, F. Forte, R. Fittipaldi, C. G. Fatuzzo, V. Granata, O. Ivashko, M. Horio, F. Schindler, M. Dantz, Yi Tseng, D. E. McNally, H. M. Rønnow, W. Wan, N. B. Christensen, J. Pelliciari, P. Olalde-Velasco, N. Kikugawa, T. Neupert, A. Vecchione, T. Schmitt, M. Cuoco, J. Chang
Format: | Article |
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Diterbitkan: | American Physical Society 2018-03-01 |
Deskripsi
The strongly correlated insulator Ca_{2}RuO_{4} is considered as a paradigmatic realization of both spin-orbital physics and a band-Mott insulating phase, characterized by orbitally selective coexistence of a band and a Mott gap. We present a high resolution oxygen K-edge resonant inelastic x-ray scattering study of the antiferromagnetic Mott insulating state of Ca_{2}RuO_{4}. A set of low-energy (about 80 and 400 meV) and high-energy (about 1.3 and 2.2 eV) excitations are reported, which show strong incident light polarization dependence. Our results strongly support a spin-orbit coupled band-Mott scenario and explore in detail the nature of its exotic excitations. Guided by theoretical modeling, we interpret the low-energy excitations as a result of composite spin-orbital excitations. Their nature unveils the intricate interplay of crystal-field splitting and spin-orbit coupling in the band-Mott scenario. The high-energy excitations correspond to intra-atomic singlet-triplet transitions at an energy scale set by Hund’s coupling. Our findings give a unifying picture of the spin and orbital excitations in the band-Mott insulator Ca_{2}RuO_{4}.