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Capacitors made of interdigitated electrodes (IDEs) as a transducer platform for the sensing of volatile organic compounds (VOCs) have advantages due to their lower power operation and fabrication using standard micro-fabrication techniques. Integrating a micro-electromechanical system (MEMS), such as a microhotplate with IDE capacitor, further allows study of the temperature-dependent sensing response of VOCs. In this paper, the design, fabrication, and characterization of a low-power MEMS microhotplate with IDE capacitor to study the temperature-dependent sensing response to methanol using Zeolitic imidazolate framework (ZIF-8), a class of metal-organic framework (MOF), is presented. A Titanium nitride (TiN) microhotplate with aluminum IDEs suspended on a silicon nitride membrane is fabricated and characterized. The power consumption of the ZIF-8 MOF-coated device at an operating temperature of 50 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C is 4.5 mW and at 200 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C it is 26 mW. A calibration methodology for the effects of temperature of the isolation layer between the microhotplate electrodes and the capacitor IDEs is developed. The device coated with ZIF-8 MOF shows a response to methanol in the concentration range of 500 ppm to 7000 ppm. The detection limit of the sensor for methanol vapor at 20 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C is 100 ppm. In situ study of sensing properties of ZIF-8 MOF to methanol in the temperature range from 20 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C to 50 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C using the integrated microhotplate and IDE capacitor is presented. The kinetics of temperature-dependent adsorption and desorption of methanol by ZIF-8 MOF are fitted with double-exponential models. With the increase in temperature from 20 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C to 50 <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mo>∘</mo> </msup> </semantics> </math> </inline-formula>C, the response time for sensing of methanol vapor concentration of 5000 ppm decreases by 28%, whereas the recovery time decreases by 70%.