Poly[[bis(nitrato-κO)bis(μ4-pyridine-4-carboxylato)tetrakis(μ3-pyridine-4-carboxylato)octasilver(I)] hemihydrate]

oleh: Zhao-Hui Meng

Format: Article
Diterbitkan: International Union of Crystallography 2011-08-01

Deskripsi

In the title coordination polymer, {[Ag8(C6H4NO2)6(NO3)2]·0.5H2O}n, two AgI ions are two-coordinate within an AgN2 set and six are three-coordinate within AgN2O and AgO3 sets. The Ag—N and Ag—O distances are in the ranges 2.150 (5)–2.198 (5) and 2.142 (4)–2.702 (5) Å, respectively. A two-dimensional coordination network is formed parallel to (100). The O atom of the disordered solvent water molecule is located on an inversion center.