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Manganiakasakaite-(La) and Ferriakasakaite-(Ce), Two New Epidote Supergroup Minerals from Piedmont, Italy
oleh: Cristian Biagioni, Paola Bonazzi, Marco Pasero, Federica Zaccarini, Corrado Balestra, Roberto Bracco, Marco E. Ciriotti
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2019-06-01 |
Deskripsi
Two new monoclinic (<i>P</i>2<sub>1</sub>/<i>m</i>) epidote supergroup minerals manganiakasakaite-(La) and ferriakasakaite-(Ce) were found in the small Mn ore deposit of Monte Maniglia, Bellino, Varaita Valley, Cuneo Province, Piedmont, Italy. Manganiakasakaite-(La) occurs as subhedral grains embedded in pyroxmangite. Its empirical formula is <i><sup>A</sup></i><sup>(1)</sup>(Ca<sub>0.62</sub>Mn<sup>2+</sup><sub>0.38</sub>) <i><sup>A</sup></i><sup>(2)</sup>(La<sub>0.52</sub>Nd<sub>0.08</sub>Pr<sub>0.07</sub>Ce<sub>0.07</sub>Y<sub>0.01</sub>Ca<sub>0.25</sub>) <i><sup>M</sup></i><sup>(1)</sup>(Mn<sup>3+</sup><sub>0.52</sub>Fe<sup>3+</sup><sub>0.28</sub>Al<sub>0.18</sub>V<sup>3+</sup><sub>0.01</sub>) <i><sup>M</sup></i><sup>(2)</sup>Al<sub>1.00</sub> <i><sup>M</sup></i><sup>(3)</sup>(Mn<sup>2+</sup><sub>0.60</sub>Mn<sup>3+</sup><sub>0.27</sub>Mg<sub>0.13</sub>) <i><sup>T</sup></i><sup>(1−3)</sup>(Si<sub>2.99</sub>Al<sub>0.01</sub>) O<sub>12</sub> (OH), corresponding to the end-member formula CaLaMn<sup>3+</sup>AlMn<sup>2+</sup>(Si<sub>2</sub>O<sub>7</sub>)(SiO<sub>4</sub>)O(OH). Unit-cell parameters are <i>a</i> = 8.9057(10), <i>b</i> = 5.7294(6), <i>c</i> = 10.1134(11) Å, β = 113.713(5)°, <i>V</i> = 472.46(9) Å<sup>3</sup>, <i>Z</i> = 2. The crystal structure of manganiakasakaite-(La) was refined to a final <i>R</i><sub>1</sub> = 0.0262 for 2119 reflections with <i>F</i><sub>o</sub> > 4σ(<i>F</i><sub>o</sub>) and 125 refined parameters. Ferriakasakaite-(Ce) occurs as small homogeneous domains within strongly inhomogeneous prismatic crystals, where other epidote supergroup minerals coexist [manganiandrosite-(Ce), “androsite-(Ce)”, and epidote]. Associated minerals are calcite and hematite. Its empirical formula is <i><sup>A</sup></i><sup>(1)</sup>(Ca<sub>0.64</sub>Mn<sup>2+</sup><sub>0.36</sub>) <i><sup>A</sup></i><sup>(2)</sup>(Ce<sub>0.37</sub>La<sub>0.17</sub>Nd<sub>0.06</sub>Pr<sub>0.03</sub>Ca<sub>0.35</sub>□<sub>0.02</sub>) <i><sup>M</sup></i><sup>(1)</sup>(Fe<sup>3+</sup><sub>0.61</sub>Al<sub>0.39</sub>) <i><sup>M</sup></i><sup>(2)</sup>Al<sub>1.00</sub> <i><sup>M</sup></i><sup>(3)</sup>(Mn<sup>2+</sup><sub>0.64</sub>Mn<sup>3+</sup><sub>0.33</sub>Fe<sup>3+</sup><sub>0.02</sub>Mg<sub>0.01</sub>) <i><sup>T</sup></i><sup>(1−3)</sup>Si<sub>3.01</sub> O<sub>12</sub> (OH), the end-member formula being CaCeFe<sup>3+</sup>AlMn<sup>2+</sup>(Si<sub>2</sub>O<sub>7</sub>)(SiO<sub>4</sub>)O(OH). Unit-cell parameters are <i>a</i> = 8.9033(3), <i>b</i> = 5.7066(2), <i>c</i> = 10.1363(3) Å, β = 114.222(2)°, <i>V</i> = 469.66(3) Å<sup>3</sup>, <i>Z</i> = 2. The crystal structure of ferriakasakaite-(Ce) was refined to a final <i>R</i><sub>1</sub> = 0.0196 for 1960 unique reflections with <i>F</i><sub>o</sub> > 4σ(<i>F</i><sub>o</sub>) and 124 refined parameters.