4-[Tris(1H-pyrazol-1-yl)methyl]phenol

oleh: Xiao-Yan Chen, Xiaoping Yang, Bradley J. Holliday

Format: Article
Diterbitkan: International Union of Crystallography 2011-11-01

Deskripsi

The title compound, C16H14N6O, was prepared by the condensation of 4-(trifluoromethyl)phenol and sodium pyrazol-1-ide in a yield of 58%. The dihedral angles formed by the planes of the pyrazole rings are 50.7 (2), 71.2 (3) and 95.8 (2)°. The molecules are associated into dimers by pairs of intermolecular O—H...N hydrogen bonds involving the hydroxy groups and pyrazole N atoms. In addition, π–π stacking between the phenol rings of these inversion-related dimers is observed, with a ring centroid-to-centroid distance of 3.9247 (10) Å.