Aerobic addition of secondary phosphine oxides to vinyl sulfides: a shortcut to 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides
oleh: Svetlana F. Malysheva, Alexander V. Artem’ev, Nina K. Gusarova, Nataliya A. Belogorlova, Alexander I. Albanov, C. W. Liu, Boris A. Trofimov
| Format: | Article |
|---|---|
| Diterbitkan: | Beilstein-Institut 2015-10-01 |
Deskripsi
Secondary phosphine oxides react with vinyl sulfides (both alkyl- and aryl-substituted sulfides) under aerobic and solvent-free conditions (80 °C, air, 7–30 h) to afford 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides in 70–93% yields.