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The development of a highly efficient, selective and atom-economical method for the construction of allylic amines are a challenge in green synthetic chemistry. In a recent work published in Nature Catalysis, Lei, Qi, and co-workers reported that the combination of a photoredox catalyst and cobaloxime catalyst enables site-selective allylic amination of various olefins with secondary alkyl amines, affording the valuable tertiary aliphatic allylamines, without the need for external oxidants.