Balloon-borne radiometer measurements of Northern Hemisphere mid-latitude stratospheric HNO3 profiles spanning 12 years

oleh: K. A. Walker, C. T. McElroy, A. I. Jonsson, C. D. Boone, P. F. Bernath, K. Strong, M. Toohey, B. M. Quine, D. Wunch

Format: Article
Diterbitkan: Copernicus Publications 2007-12-01

Deskripsi

Low-resolution atmospheric thermal emission spectra collected by balloon-borne radiometers over the time span of 1990&ndash;2002 are used to retrieve vertical profiles of HNO<sub>3</sub>, CFC-11 and CFC-12 volume mixing ratios between approximately 10 and 35 km altitude. All of the data analyzed have been collected from launches from a Northern Hemisphere mid-latitude site, during late summer, when stratospheric dynamic variability is at a minimum. The retrieval technique incorporates detailed forward modeling of the instrument and the radiative properties of the atmosphere, and obtains a best fit between modeled and measured spectra through a combination of onion-peeling and optimization steps. The retrieved HNO<sub>3</sub> profiles are consistent over the 12-year period, and are consistent with recent measurements by the Atmospheric Chemistry Experiment-Fourier transform spectrometer satellite instrument. We therefore find no evidence of long-term changes in the HNO<sub>3</sub> summer mid-latitude profile, although the uncertainty of our measurements precludes a conclusive trend analysis.