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Structural feature of graphene-like graphitic carbon nitride nanosheets synthesized <i>via</i> high-energy microwave irradiation
oleh: ZOU Jing-ye, YU Yong-zhi, GU Yong-pan, YUE Xia-wei, MENG Jiang, LI Shu-ping, WANG Ji-gang
| Format: | Article |
|---|---|
| Diterbitkan: | Journal of Materials Engineering 2019-03-01 |
Deskripsi
Microwave synthesis has many advantages covering rapid, high-efficient, environmentally-friendly <i>etc</i>. Herein, graphene-like carbon nitride nanosheets (g-C<sub>3</sub>N<sub>4</sub>-NS) were successfully prepared by high-energy microwave heating method using melamine and carbon fibers as precursor and microwave absorber, respectively. The as-synthesized samples were investigated <i>via</i> various analytic techniques including X-ray diffraction (XRD), field-emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM) and fourier transform infrared spectroscopy (FT-IR). Results show that the g-C<sub>3</sub>N<sub>4</sub>-NS sample prepared by microwave heating exhibits the obvious feature of graphene-like ultra-thin nanosheets in comparison with sample synthesized by conventional thermal polycondensation. Meanwhile, compared with graphene-like carbon nitride nanosheets prepared by other approaches including ultrasonic exfoliation and oxidation etching methods, the sample synthesized by microwave heating has smooth, flat and strong rigidity surface.