catena-Poly[[[bis(acetato-κ2O,O′)aquacadmium]-μ-[(pyridin-3-yl)(pyridin-4-yl)methanone]-κ2N:N′] dihydrate]
oleh: Zhi-Wei Wang, Ai-Min Li, Ya Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-06-01 |
Deskripsi
In the title complex, {[Cd(CH3COO)2(C11H8N2O)(H2O)]·2H2O}n, the CdII ion adopts an O5N2 pentagonal–bipyramidal coordination geometry with four acetate O atoms and one water O atom at the equatorial sites and two pyridine N atoms at the axial sites. The (pyridin-3-yl)(pyridin-4-yl)methanone ligand acts in a μ2-bridging mode, linking the metal atoms, leading to an infinite chain along [-110]. O—H...O hydrogen bonds involving the lattice water molecules connect these chains into a three-dimensional network.