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trans-Bis(5,5-diphenylhydantoinato-κN3)bis(propane-1,2-diamine-κ2N,N′)nickel(II)
oleh: Xiaojiao Li, Daqi Wang, Xingyou Xu, Xilan Hu
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2008-12-01 |
Deskripsi
The asymmetric unit of the title complex, [Ni(pht)2(pn)2] (pht is 5,5-diphenylhydantoinate and pn is propane-1,2-diamine) or [Ni(C15H11N2O2)2(C3H10N2)2], contains one-half [Ni(pht)2(pn)2] molecule. The NiII atom is situated on a crystallographic center of inversion and shows a distorted octahedral coordination geometry. A three-dimensional network structure is assembled by inter- and intramolecular N—H...O=C interactions.