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Applied Stress-Assisted Growth of Single Crystal γ-Fe<sub>2</sub>O<sub>3</sub> Nanowires
oleh: Lan Lu, Ligen Hong, Yi Chu, Huayong Pan, Shaoyun Huang, Yingjie Xing, Hongqi Xu
Format: | Article |
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Diterbitkan: | MDPI AG 2018-12-01 |
Deskripsi
It is difficult to obtain γ-Fe<sub>2</sub>O<sub>3</sub> nanostructures by heating iron substrate in ambient conditions because γ-Fe<sub>2</sub>O<sub>3</sub> is less thermodynamically stable than α-Fe<sub>2</sub>O<sub>3</sub>. In this work, we synthesize γ-Fe<sub>2</sub>O<sub>3</sub> nanowires by heating iron particles under an external force. The stacking style of iron and oxygen ions under a strong shearing stress tends to adopt the γ-Fe<sub>2</sub>O<sub>3</sub> structure regardless of the thermodynamic restriction. These γ-Fe<sub>2</sub>O<sub>3</sub> nanowires exhibit a clear ferromagnetic property. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) measurements confirm that γ-phase structure appears only under the applied external force during the heating period. A window of the magnitude of the external force is found to help the nanowire growth on iron particles. The growth mechanism of γ-Fe<sub>2</sub>O<sub>3</sub> nanowires other than α-Fe<sub>2</sub>O<sub>3</sub> under the external force is discussed and an applied stress-assisted growth model is proposed. This work presents an easy approach to produce ferromagnetic iron oxide nanowires on a large scale.