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Exploring the spatial distribution of the multi-fractal scaling behaviours in atmospheric CO₂ concentration time series is useful for understanding the dynamic mechanisms of carbon emission and absorption. In this work, we utilise a well-established multi-fractal detrended fluctuation analysis to examine the multi-fractal scaling behaviour of a column-averaged dry-air mole fraction of carbon dioxide (XCO₂) concentration time series over China, and portray the spatial distribution of the multi-fractal scaling behaviour. As XCO₂ data values from the Greenhouse Gases Observing Satellite (GOSAT) are insufficient, a spatio-temporal thin plate spline interpolation method is applied. The results show that XCO₂ concentration records over almost all of China exhibit a multi-fractal nature. Two types of multi-fractal sources are detected. One is long-range correlations, and the other is both long-range correlations and a broad probability density function; these are mainly distributed in southern and northern China, respectively. The atmospheric temperature and carbon emission/absorption are two possible external factors influencing the multi-fractality of the atmospheric XCO₂ concentration. <b>Highlight</b>: (1) An XCO₂ concentration interpolation is conducted using a spatio-temporal thin plate spline method. (2) The spatial distribution of the multi-fractality of XCO₂ concentration over China is shown. (3) Multi-fractal sources and two external factors affecting multi-fractality are analysed.