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catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphthyl)methylene]glycinato]
oleh: Ling-Wei Xue, Xing-Wu Li, Gan-Qing Zhao, Qin-Long Peng
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2009-10-01 |
Deskripsi
In the title compound, [Cu(C13H9NO3)(C5H5N)], the CuII atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu—O bond [2.3520 (16) Å] is much longer than the basal Cu—O and Cu—N bonds [1.9139 (14)–2.0136 (17) Å]. The carboxylate group bridges CuII atoms, forming a zigzag chain along the a axis.