catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphthyl)methylene]glycinato]

oleh: Ling-Wei Xue, Xing-Wu Li, Gan-Qing Zhao, Qin-Long Peng

Format: Article
Diterbitkan: International Union of Crystallography 2009-10-01

Deskripsi

In the title compound, [Cu(C13H9NO3)(C5H5N)], the CuII atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu—O bond [2.3520 (16) Å] is much longer than the basal Cu—O and Cu—N bonds [1.9139 (14)–2.0136 (17) Å]. The carboxylate group bridges CuII atoms, forming a zigzag chain along the a axis.