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trans-Bis(acetato-κO)bis(2-aminoethanol-κ2N,O)nickel(II)
oleh: Mahdi Seifollahi Bazarjani, Ralf Riedel, Aleksander Gurlo, Wolfgang Donner, Sabine Foro
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2012-05-01 |
Deskripsi
In the title compound, [Ni(CH3CO2)2(C2H7NO)2], the NiII cation, located on an inversion center, is N,O-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramolecular O—H...O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hydroxy group of the 2-aminoethanol ligand. In the crystal, N—H...O hydrogen bonds link the molecules into a three-dimensional supramolecular framework that involves (a) the coordinated acetate O atom and one of the H atoms of the amino group and (b) the non-coordinated acetate O atom and the other H atom of the amino group.