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Abstract We study scalarization of spherically symmetric neutral reflecting shells in the scalar-tensor gravity. We consider neutral static massless scalar fields non-minimally coupled to the Gauss–Bonnet invariant. We obtain a relation representing the existence regime of hairy neutral reflecting shells. For parameters unsatisfying this relation, the massless scalar field cannot exist outside the neutral reflecting shell. In the parameter region where this relation holds, we get analytical solutions of scalar field hairs outside neutral reflecting shells.