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The minimal length of a plateau (a sequence of horizontal steps, preceded by an up- and followed by a down-step) in a Motzkin path is known to be of interest in the study of secondary structures which in turn appear in mathematical biology. We will treat this and the related parameters <i> maximal plateau length, horizontal segment </i>and <i>maximal horizontal segment </i>as well as some similar parameters in unary-binary trees by a pure generating functions approach―-Motzkin paths are derived from Dyck paths by a substitution process. Furthermore, we provide a pretty general analytic method to obtain means and limiting distributions for these parameters. It turns out that the maximal plateau and the maximal horizontal segment follow a Gumbel distribution.