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Effective particle density is a key parameter for assessing inhalation exposure of engineered NPs in occupational environments. In this paper, particle density measurements were carried out using two different techniques: one based on the ratio between mass and volumetric particle concentrations; the other one based on the ratio between aerodynamic and geometric particle diameter. These different approaches were applied to both field- and laboratory-scale atomization processes where the two target NPs (N-doped TiO₂, TiO₂N and AgNPs capped with a quaternized hydroxyethylcellulose, AgHEC) were generated. Spray tests using TiO₂N were observed to release more and bigger particles than tests with AgHEC, as indicated by the measured particle mass concentrations and volumes. Our findings give an effective density of TiO₂N particle to be in a similar range between field and laboratory measurements (1.8 ± 0.5 g/cm³); while AgHEC particle density showed wide variations (3.0 ± 0.5 g/cm³ and 1.2 + 0.1 g/cm³ for field and laboratory campaigns, respectively). This finding leads to speculation regarding the composition of particles emitted because atomized particle fragments may contain different Ag-to-HEC ratios, leading to different density values. A further uncertainty factor is probably related to low process emissions, making the subtraction of background concentrations from AgHEC process emissions unreliable.