(Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO2)benzohydrazidato-κ2N′,O]oxidovanadium(V)
oleh: Xiao-Hua Chen, Qiong-Jie Wu, Li-Juan Chen, Ming-Xing Yang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-08-01 |
Deskripsi
In the title complex, [V(C15H12N2O4)(C2H5O)O], the VV ion is coordinated by an oxide O atom, an ethanolate anion and two O atoms and one N atom from the tridentate benzohydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intramolecular O—H...N hydrogen bond occurs in the benzohydrazidate ligand. Weak intermolecular C—H...O hydrogen bonding is present in the crystal.