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Bis(triethylammonium) tetrachloridocobaltate(II)
oleh: Reza Azadbakht, Hassan Hadadzadeh, Hadi Amiri Rudbari
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2012-06-01 |
Deskripsi
The crystal structure of the title compound, (C6H16N)2[CoCl4], is comprised of a tetrahedral [CoCl4]2− anion and two independent triethylammonium cations. The latter are featureless while the [CoCl4]2− anion exhibits typical Co—Cl bond lengths [2.2428 (15)–2.2847 (16) Å] and a Cl—Co—Cl angular range of 107.58 (6)–112.73 (7)°. In the crystal, N—H...Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl4]2− anion generate discrete ion triplets. The two Co—Cl bonds involved in these interactions are slightly longer than the remaining two.