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This paper investigates the mean-square exponential synchronization issues of delayed stochastic complex dynamical networks with switching topology and impulsive control. By using the Lyapunov functional method, impulsive control theory, and linear matrix inequality (LMI) approaches, some sufficient conditions are derived to guarantee the mean-square exponential synchronization of delay complex dynamical network with switch topology, which are independent of the network size and switch topology. Numerical simulations are given to illustrate the effectiveness of the obtained results in the end.