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Intercalation is an established technique for tailoring the electronic structure of epitaxial graphene. Moreover, it enables the synthesis of otherwise unstable two-dimensional (2D) layers of elements with unique physical properties compared to their bulk versions due to interfacial quantum confinement. In this work, we present uniformly Pb-intercalated quasifreestanding monolayer graphene on SiC, which turns out to be essentially charge neutral with an unprecedented p-type carrier density of only (5.5±2.5)×10^{9} cm^{−2}. Probing the low-energy electronic structure throughout the entire first surface Brillouin zone by means of momentum microscopy, we clearly discern additional bands related to metallic 2D Pb at the interface. Low-energy electron diffraction further reveals a 10×10 Moiré superperiodicity relative to graphene, counterparts of which cannot be directly identified in the available band structure data. Our experiments demonstrate 2D interlayer confinement and associated band structure formation of a heavy-element superconductor, paving the way towards strong spin-orbit coupling effects or even 2D superconductivity at the graphene-SiC interface.