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Self-luminous magnesium phosphate cement is a new material that combines long-afterglow luminescent material with magnesium phosphate cement. This paper studies the performance of self-luminous magnesium phosphate cement material through experiments, so as to expand the applicability of this material to exterior walls of buildings in a cold climate. The experiment indicates that the Self-luminous magnesium phosphate cement has excellent corrosion resistance, impermeability, and salt-freeze resistance in a cold climate. It can be used as a new kind of beautiful, energy-saving and environment-friendly exterior wall paving material.