catena-Poly[[[aquacopper(II)]bis[μ-bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide]] bis(tetrafluoridoborate) bis(triphenylphosphine oxide) monohydrate]
oleh: Maksym Seredyuk, Kateryna O. Znovjyak, Yurii S. Moroz, Vadim A. Pavlenko, Igor O. Fritsky
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-05-01 |
Deskripsi
The title compound, {[Cu(C10H14N4Se)2(H2O)](BF4)2·2C18H15PO·H2O}n, has a polymeric structure where each CuII ion adopts a square-pyramidal coordination constituted by four N atoms of pyrazole moieties in the equatorial plane and an axial O atom of a water molecule. A pair of bis(3,5-dimethyl-1H-pyrazol-4-yl) selenide ligands bridges the CuII centres into a chain extending along the c axis. The water molecules, anions and triphenylphosphine oxide molecules are involved in intermolecular hydrogen bonding, which links the chains into a three-dimensional network.