catena-Poly[{μ-cyanido-bis[(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(I)]}-μ-cyanido-copper(I)-μ-cyanido]
oleh: Shi-Hong Lin, Ying-Yi Yang, Seik Weng Ng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-08-01 |
Deskripsi
In the title compound, [Cu3(CN)3(C12H12N2)2], two 2,2′-bipyridine N,N′-chelated CuI atoms are linked by a cyanide bridge that lies about a center of inversion; the CuI atom exists in a tetrahedral coordination geometry. This dinuclear entity is linked to another CuI atom that lies on a twofold rotation axis by another cyanide bridge, these bridges giving rise to the formation of a linear chain motif.