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Bis[4-(2-azaniumylethyl)piperazin-1-ium] di-μ-sulfido-bis[disulfidogermanate(II)]
oleh: Bei-Bei Zhang, Chao Xu, Taike Duan, Qun Chen, Qian-Feng Zhang
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2012-06-01 |
Deskripsi
In the title compound, (C6H17N3)2[Ge2S6], the dimeric [Ge2S6]4− anion is formed by two edge-sharing GeS4 tetrahedral units. The average terminal and bridging Ge—S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N—H...S hydrogen bonds.