Metal-organic framework glasses with permanent accessible porosity

oleh: Chao Zhou, Louis Longley, Andraž Krajnc, Glen J. Smales, Ang Qiao, Ilknur Erucar, Cara M. Doherty, Aaron W. Thornton, Anita J. Hill, Christopher W. Ashling, Omid T. Qazvini, Seok J. Lee, Philip A. Chater, Nicholas J. Terrill, Andrew J. Smith, Yuanzheng Yue, Gregor Mali, David A. Keen, Shane G. Telfer, Thomas D. Bennett

Format: Article
Diterbitkan: Nature Portfolio 2018-11-01

Deskripsi

Metal–organic framework glasses have emerged as a new family of melt-quenched glass, but have yet to display the accessible porosity of their crystalline counterparts. Here, Bennett and colleagues report that glasses derived from ZIF-76 parent materials possess 4 – 8 Å pores and exhibit reversible gas adsorption.